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Which of the following is wrong ?...

Which of the following is wrong ?

A

`NH_(3) lt PH_(3) lt AsH_(3)` (acidic character)

B

`Li lt Be lt B lt C(IE_(1))`

C

`A1_(2)O_(3) lt MgO lt Na_(2)O lt K_(2)O` (basic)

D

`Li^(+) lt Na^(+) lt K^(+) lt Cs^(+)` (inoic radius)

Text Solution

Verified by Experts

The correct Answer is:
B

`B` has unusually low `IE_(1)` than `Be` because in `B`. The ionized electron is a `p` electron from the `2nd` shell while in `Be`, the ionized electron is an `s` electron from the `2nd` shell. For a given value of `n`, the case of removal of electron is
`sgt p gt dgt f`
The correct order is
`Li (520 kJ mol^(-1)) lt B (801) lt Be (899) lt C (1086)`
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