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Shape and hybridization of IF5, respecti...

Shape and hybridization of `IF_5`, respectively, are

A

pentagonal pyramidal, `sp^3d^3`

B

square pyramidal, `sp^3d^2`

C

seesaw, `sp^3d`

D

trigonal bipyramidal, `sp^3d`

Text Solution

Verified by Experts

The correct Answer is:
B

Ground-state valence shell electron configuration of `I` is `5s^2 5p^5`. Thus, it has 7 valence electrons, 5 valence `e^(-)s` are used to hold 5 F atoms while 2 valence `e^(-)s` form one lone pair of electrons. Thus, its steric number is `5+1=6`. This implies `sp^3d^2` hybridization, octahedral geometry, and square pyramidal shape (due to one lone pair).
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