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Arrange the following ions in the order ...

Arrange the following ions in the order of decreasing `X-O` bond length where X is the central atom:

A

`ClO_4^(-), SO_4^(2-), PO_4^(3-), SiO_4^(4-)`

B

`SiO_4^(4-), PO_4^(3-), SO_4^(2-), ClO_4^(-)`

C

`SiO_4^(4-), PO_4^(3-), ClO_4^(-), SO_4^(2-)`

D

`SiO_4^(4-), SO_4^(2-), PO_4^(3-), ClO_4^(-)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of arranging the given ions in the order of decreasing X-O bond length, we need to consider the following factors: 1. **Electronegativity**: The bond length generally decreases with increasing electronegativity of the central atom (X). More electronegative atoms pull the bonding electrons closer, resulting in shorter bond lengths. 2. **Atomic Size**: Larger atoms will have longer bond lengths. Therefore, if the central atom (X) is larger, the bond length will be longer. 3. **Formal Charge**: Ions with higher positive formal charges typically have shorter bond lengths due to increased attraction between the central atom and oxygen. ### Step-by-Step Solution: **Step 1: Identify the Central Atom (X) and the Ions** - Let's assume we have the following ions: \( \text{X}_1O^-, \text{X}_2O^{2-}, \text{X}_3O^{2-}, \text{X}_4O^{3-} \) where \( \text{X}_1, \text{X}_2, \text{X}_3, \text{X}_4 \) are different central atoms. **Step 2: Compare the Central Atoms** - Determine the electronegativity and atomic size of each central atom. For example, if \( \text{X}_1 \) is a larger atom compared to \( \text{X}_2 \), then \( \text{X}_1O^- \) will have a longer bond length than \( \text{X}_2O^{2-} \). **Step 3: Consider the Charge on the Ions** - The charge on the ions will also affect the bond length. For example, \( O^{2-} \) will have a stronger attraction to a positively charged central atom than \( O^- \). **Step 4: Arrange the Ions Based on Bond Length** - After considering the above factors, arrange the ions in order of decreasing bond length. For instance, if \( \text{X}_1O^- \) has the longest bond length, followed by \( \text{X}_2O^{2-} \), and so on, the final order will be: - \( \text{X}_1O^- > \text{X}_2O^{2-} > \text{X}_3O^{2-} > \text{X}_4O^{3-} \) ### Final Answer: The order of decreasing X-O bond length is: \[ \text{X}_1O^- > \text{X}_2O^{2-} > \text{X}_3O^{2-} > \text{X}_4O^{3-} \]

To solve the problem of arranging the given ions in the order of decreasing X-O bond length, we need to consider the following factors: 1. **Electronegativity**: The bond length generally decreases with increasing electronegativity of the central atom (X). More electronegative atoms pull the bonding electrons closer, resulting in shorter bond lengths. 2. **Atomic Size**: Larger atoms will have longer bond lengths. Therefore, if the central atom (X) is larger, the bond length will be longer. 3. **Formal Charge**: Ions with higher positive formal charges typically have shorter bond lengths due to increased attraction between the central atom and oxygen. ...
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