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In TeCl4, the central tellurium involves...

In `TeCl_4`, the central tellurium involves the hybridization

A

`sp^3`

B

`sp^3d`

C

`sp^3d^2`

D

`dsp^2`

Text Solution

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The correct Answer is:
To determine the hybridization of the central tellurium atom in TeCl₄ (tellurium tetrachloride), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Central Atom**: - The central atom in TeCl₄ is tellurium (Te). 2. **Determine the Group of Tellurium**: - Tellurium is in Group 16 of the periodic table. 3. **Count Valence Electrons**: - Elements in Group 16 have 6 valence electrons. Therefore, tellurium has 6 valence electrons. 4. **Count the Number of Chlorine Atoms**: - TeCl₄ has 4 chlorine (Cl) atoms bonded to the tellurium atom. 5. **Determine Electrons Used for Bonding**: - Each chlorine atom forms a single covalent bond with tellurium, which means tellurium uses 4 of its valence electrons to bond with the 4 chlorine atoms. 6. **Calculate Remaining Valence Electrons**: - After forming 4 bonds, tellurium has 6 - 4 = 2 valence electrons left. 7. **Identify Lone Pairs**: - The remaining 2 valence electrons will form a lone pair on the tellurium atom. 8. **Determine the Steric Number**: - The steric number is calculated by adding the number of bonded atoms to the number of lone pairs. - Here, there are 4 bonded chlorine atoms and 1 lone pair: - Steric Number = 4 (bonded atoms) + 1 (lone pair) = 5. 9. **Determine Hybridization**: - The hybridization corresponding to a steric number of 5 is sp³d. 10. **Identify the Geometry**: - The geometry of a molecule with sp³d hybridization and a steric number of 5 is trigonal bipyramidal. ### Final Answer: The central tellurium in TeCl₄ involves **sp³d hybridization**. ---

To determine the hybridization of the central tellurium atom in TeCl₄ (tellurium tetrachloride), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Central Atom**: - The central atom in TeCl₄ is tellurium (Te). 2. **Determine the Group of Tellurium**: ...
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