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Which of the following is not isostruct...

Which of the following is not isostructural with `SiCI_(4)` ?

A

`PO_4^(3-)`

B

`NH_4^(+)`

C

`SCl_4`

D

`SO_4^(2-)`

Text Solution

Verified by Experts

The correct Answer is:
C

`SN` of `Si` in `SiCl_4` is `4+0=4`, therefore, it is tetrahedral. `SN` of `P` in `PO_4^(3-)` is `4+0=4` (tetrahedral), `SN` of `N` in `NH_4^(+)` is `4+0=4` (tetrahedral), `SN` of `S` in `SCl_4` is `4+1=5` (seesaw), and `SN` of `S` in `SO_4^(2-)` is `4+0=4` (tetrahedral).
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