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Which of these is not a monomer for a hi...

Which of these is not a monomer for a high-molecular mass silicone polymer?

A

`Me_(2)SiCl_(2)`

B

`Me_(3)SiCl`

C

`PhSiCl_(3)`

D

`MeSiCl_(3)`

Text Solution

Verified by Experts

The correct Answer is:
B

The hydrolysis of `(CH_(3))_(3)SiCl` gives `(CH_(3))_(3)SiOH` which condenses to give a dimer:
`CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(Si)-OH+HO-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(Si)-CH_(3)overset(-H_(2)O)rarr`
`CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(Si)-O-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(Si)-CH_(3)`
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