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Given the IUPAC names of the following h...

Given the `IUPAC` names of the following haloalkanes and label them as primary `(1^(@))`, secondary `(2^(@))`, or tertiary `(3^(@))`
(i) tert-pentylioddie
(ii) `CH_(3)CH_(2)underset(Cl)underset(|)CHoverset(CH_(3))overset(|)(CH)CH_(3)`
(iii) Isobutyl chloride
(iv) `n`-butyl bromide
(v) `CH_(3)CH_(2)-underset(Br)underset(|)overset(CH_(3))overset(|)C-CH_(2)-overset(CH_(3))overset(|)(CH)-CH_(3)`
Isopropyl chloride
Strategy: For common names, first write the sturucture of the alkyl group, and then attach the halgon atom to the free valency.

Text Solution

Verified by Experts

(i) `Coverset(4)H_(3)Coverset(3)H_(2)-underset(I)underset(|)overset(CH_(3))overset(2|)C-overset(1)CH_(3)`
(ii) `3`-Chloro-`2`-methylpentane `(2^(@))`
(iii) `Coverset(3)H_(3)-underset(CH_(3))underset(|)overset(2)(CH)-overset(1)CH_(2)-Cl`
`1`-Chlo romethylpro pan e(`1^(@))`
(iv) `CH_(3)CH_(2)CH_(2)-Br 1`-Bromobutane `(1^(@))`
(v) 4-Bromo-2,4-dimethylhexane `(3^(@))`
(vi) `CH_(3)-CH-CH_(3) 2`-Chloropropane `(2^(@))`
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