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Which of the following orbital overlaps ...

Which of the following orbital overlaps is involved in the formation of the carbon-carbon signle bond in the molecule
`HC -= C - CH = CH_(2)` ?

A

(1) `sp^(3) - sp^(3)`

B

(2) `sp^(2) - sp^(3)`

C

(3) `sp - sp^(2)`

D

(4) `sp^(3) - sp`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the type of orbital overlap involved in the formation of the carbon-carbon single bond in the molecule \( HC \equiv C - CH = CH_2 \), we can follow these steps: ### Step 1: Identify the Structure of the Molecule The given molecule is \( HC \equiv C - CH = CH_2 \). It contains a carbon-carbon triple bond between the first two carbon atoms and a carbon-carbon double bond between the last two carbon atoms. ### Step 2: Identify the Hybridization of Each Carbon Atom 1. **C1 (first carbon)**: This carbon is involved in a triple bond with C2 and a single bond with H. - **Steric Number**: 2 (1 triple bond with C2 and 1 single bond with H) - **Hybridization**: Since the steric number is 2, the hybridization is \( sp \). 2. **C2 (second carbon)**: This carbon is involved in a triple bond with C1 and a single bond with C3. - **Steric Number**: 3 (1 triple bond with C1 and 1 single bond with C3) - **Hybridization**: Since the steric number is 3, the hybridization is \( sp^2 \). 3. **C3 (third carbon)**: This carbon is involved in a single bond with C2 and a double bond with C4. - **Steric Number**: 3 (1 single bond with C2 and 1 double bond with C4) - **Hybridization**: Since the steric number is 3, the hybridization is \( sp^2 \). 4. **C4 (fourth carbon)**: This carbon is involved in a double bond with C3 and two single bonds with H. - **Steric Number**: 3 (1 double bond with C3 and 2 single bonds with H) - **Hybridization**: Since the steric number is 3, the hybridization is \( sp^2 \). ### Step 3: Identify the Overlap in the Carbon-Carbon Single Bond The carbon-carbon single bond in the molecule is between C2 and C3. - C2 has \( sp^2 \) hybridization. - C3 also has \( sp^2 \) hybridization. ### Step 4: Determine the Type of Orbital Overlap The overlap that forms the single bond between C2 and C3 is between the \( sp^2 \) hybrid orbital of C2 and the \( sp^2 \) hybrid orbital of C3. ### Conclusion Thus, the orbital overlap involved in the formation of the carbon-carbon single bond in the molecule \( HC \equiv C - CH = CH_2 \) is \( sp^2 - sp^2 \) overlap. ### Final Answer The correct option is: **\( sp^2 - sp^2 \) orbital overlap.** ---

To determine the type of orbital overlap involved in the formation of the carbon-carbon single bond in the molecule \( HC \equiv C - CH = CH_2 \), we can follow these steps: ### Step 1: Identify the Structure of the Molecule The given molecule is \( HC \equiv C - CH = CH_2 \). It contains a carbon-carbon triple bond between the first two carbon atoms and a carbon-carbon double bond between the last two carbon atoms. ### Step 2: Identify the Hybridization of Each Carbon Atom 1. **C1 (first carbon)**: This carbon is involved in a triple bond with C2 and a single bond with H. - **Steric Number**: 2 (1 triple bond with C2 and 1 single bond with H) ...
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R SHARMA-NOMENCLATURE OF ORGANIC COMPOUNDS-Question Bank
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