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During the testing for phosphorus in org...

During the testing for phosphorus in organic compounds, a yellow solution or precipitate is formed due to the formation of

A

ammonium phosphate

B

ammonium molybdate

C

ammonium phosphomolybdate

D

sodium phosphate

Text Solution

Verified by Experts

The correct Answer is:
C
The yellow solution or precipitate is of ammonium phosphomolydate `(NH_(4))_(3)[PO_(4).12M0O_(3)]` or `[NH_(4)]_(3) [PMo_(12)O_(40)]`
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Knowledge Check

  • Here paragraphs are given. Based upon the paragraphs some multiple choice questions are given. Each question has 4 choices A, B, C and D. Out of which one is correct. Choose the correct option Paragraph/comprehension In the detection of elements by Lassaigne’s test, the covalent compounds are converted into ionic compounds on fusion with sodium metal. The nitrogen, sulphur and halides present in the organic compounds are test with their usual tests. In this test blue or green colour is obtained when only nitrogen is present whereas red colour is obtained when both nitrogen and sulphur are present. The Lassaigne’s extract is boiled with HNO_(3) so as to decompose Na_(2) and NaCN if present. Phosphorus is detected in the organic compound by fusing it with sodium peroxide. When sodium phosphate formed is detected with cone. HNO_(3) and ammonium molybdate. During detection of phosphours in an organic compound,yellow precipitate are formed due to the formation of

    A
    `(NH_(4))_(3)PO_(4)`
    B
    `(NH_(4))_(2)MoO_(4)`
    C
    `MgNH_(4)PO_(4)`
    D
    `(NH_(4))_(3)PO_(4).12moO_(3)`

  • When FeCl_(3) is added to the sodium extract of an organic compound containing both N and S, the red coloured precipitate is formed due to the formation of

    A
    `[Fe(CN)_(6)]^(3-)`
    B
    `[Fe(CNS)]^(2+)`
    C
    `[Fe(CNS)_(2)]^(+)`
    D
    `[Fe(CN)_(6)]^(4-)`

  • In the Lassaignes test for the detection of nitrogen in an organic compound, the blue or green colour is due to the formation of

    A
    `K_(3)[Fe(CN)_(6)]`
    B
    `K_(4)[Fe(CN)_(6)]`
    C
    `Fe(CN)_(6)`
    D
    `Fe[Fe(CN)_(6)]_(3)`

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