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An organic compound contains C, H, and O...

An organic compound contains `C, H`, and `O`. Its elemental analysis gave `C(38.71%)` and `H (9.67%)`. The empirical formula of the compound will be

A

`CH_(4)O`

B

`CH_(3)O`

C

`CHO`

D

`CH_(2)O`

Text Solution

Verified by Experts

The correct Answer is:
B

`% O = 100% - (% C + % H)`
`= 100% - 48.38% = 51.62%`
Considering `100 g` of compound, we have, `m_(C) = 38.71 g`, `m_(H) = 9.67 g, m_(O) = 51.62g`
Thus,
`n_(C) : n_(H) : n_(O) = (38.71 g)/(12 g mol^(-1)) : (9.67 g)/(1 g mol^(-1)) : (51.62 g)/(16 g mol^(-1))`
`= 3.226 : 9.67 : 3.226`
`= (3.226)/(3.226):(9.67)/(3.226):(3.226)/(3.226)`
`= 1:3:1`
Empirical formula is `CH_(3)O`.
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