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The total number of contributing structu...

The total number of contributing structures for hyperconjugation in propene is

A

3

B

4

C

5

D

2

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To find the total number of contributing structures for hyperconjugation in propene, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure of Propene**: Propene has the molecular formula C₃H₆ and its structure can be represented as: \[ \text{CH}_2= \text{CH}-\text{CH}_3 \] In this structure, we have a double bond between the first two carbon atoms. 2. **Identify the Hybridization**: - The first carbon (C1) and the second carbon (C2) are sp² hybridized. - The third carbon (C3) is sp³ hybridized. 3. **Identify Alpha-Hydrogens**: - Alpha-hydrogens are the hydrogens attached to the carbon atoms adjacent to the double bond (sp² hybridized carbons). - In propene, the alpha-hydrogens are those attached to C1 and C2. - C1 has 2 alpha-hydrogens (attached to C1) and C2 has 1 alpha-hydrogen (attached to C2). - Therefore, the total number of alpha-hydrogens = 2 (from C1) + 1 (from C2) = 3. 4. **Calculate the Number of Contributing Structures**: - The total number of contributing structures for hyperconjugation can be calculated using the formula: \[ \text{Number of hyperconjugation structures} = \text{Number of alpha-hydrogens} + 1 \] - Substituting the number of alpha-hydrogens: \[ \text{Number of hyperconjugation structures} = 3 + 1 = 4 \] 5. **Conclusion**: The total number of contributing structures for hyperconjugation in propene is **4**.

To find the total number of contributing structures for hyperconjugation in propene, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure of Propene**: Propene has the molecular formula C₃H₆ and its structure can be represented as: \[ \text{CH}_2= \text{CH}-\text{CH}_3 ...
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The total number of contributing structures showing hyperconjugation (involving C-H bonds) for the following carbocation is:

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Knowledge Check

  • Hyperconjugation is

    A
    `sigma-pi` conjugation
    B
    noticed due to delocalisation of `sigma and pi` bond
    C
    no bond resonance
    D
    all the above
  • The number of hyperconjugating structures shown by the carbocations are given below. WhJch one is not correctly matched ?

    A
    `CH_(3)-overset(+)underset(CH_(3))underset(|)C-CH_(3)-9` hyperconjugating structures
    B
    `CH_(3)-overset(+)CH-CH_(3)-8` hyperconjugating structures
    C
    `CH_(3)-overset(+)CH_(2)-3` hyperconjugating structures
    D
    `overset(+)CH_(3)-`No hyperconjugating structures
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    The total number of contributing structures showing hyperconjugation (involving C-H bonds) for the carbocation given on R.H.S. is

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    Hyperconjugation describes the orbital interactions between the pi -system and the adjacent sigma -bond of the substituent group(s) in organic compounds. Hyperconjugation is called as Baker and Nathan effect. The necessary and sufficient conditions for the hyperconjugation are: (i) Compound should have at least one sp^(2) -hybrid carbon of either alkene, carbocation or alkyl free radical. (ii) alpha -carbon with respect to sp^(2) -hybrid carbon should have at least one hydrogen. Hyperconjugation are of three types: (i) sigma(C-H),pi -conjugation, (ii) sigma(C-H), positive charge conjugation, (iii) sigma(C-H) , odd electron conjugation. The hyperconjugation may be represented as, Number of resonating structures due to hyperconjugation =(n+1) , where n is the numebr of alpha -hydrogen. Greater is the number of such forms, more is the stability of the species under consideration. Which of the following alkenes will show maximum number of hyperconjugation forms?

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