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Strutural isomers C2H5OH and CH3OCH3 hav...

Strutural isomers `C_2H_5OH` and `CH_3OCH_3` have the same value of

A

boiling points

B

heat of vaporization

C

gaseous densities at the same temperature and pressure

D

vapor pressure at the same temperature

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The correct Answer is:
C

`C_2H_5OH` exhibits intermolecular H bonding while `CH_3OCH_3` does not exhibit intermolecular H bonding Thus, they have different values of (1), (2), and (4) becase of same molecular mass, they have same gaseous dendities at the same T and `P(d=(PM)/(RT))`
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C_2H_5OH and CH_3OCH_3 are

The heat of formation of C_(2)H_(5)OH(l) is -66Kcal//mol . The heat of combustion of CH_(3)OCH_(3)(g) is -348Kcal//mol , DeltaH_(f) for H_(2)O and CO_(2) are -68Kcal//mol and -94Kcal//mol . Respectively. Then, the DeltaH for the isomerisation reaction C_(2)H_(5)OH(l)rarrCH_(3)OCH_(3)(g) , and DeltaE for the same are at T=25^(@)C

The heat of formation of C_(2)H_(5)OH(l) is -66 kcal//"mole" . The heat of combustion of CH_(3)OCH_(3) (g) is -348 kcal/mole. DeltaH_(f) for H_(2)O and CO_(2) are -68 kcal/mole respectively. Then, the Delta H for the isomerisation reaction C_(2)H_(5)OH(l)rarrCH_(3)OCH_(3)(g) ,and Delta E for the same are at T=25^(@)C

Which of the following parameteres would be expected to have the same values for C_(2)H_(5)OH and CH_(3)OCH_(3) ?

CH_(3)OCH_(3) is a gas at room temperature while its isomer CH_(3)CH_(2)OH is a liquid of boiling point 78^(@)C this is due to the fact that

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