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`Ph-overset(O)overset(||)(C)-underset(..)overset(..)(O)-` is an activator as well as orthopara director while `-overset(O)overset(||)(C)-OPh` is a deactivator as well as meta director thus,ring 2 is more electron rich andon mononitration, electrophilic substitution takes place on ring 2. para product is preferred on account of steric hindrance and stronger `-I` effect of O atom at the ortho position.