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Benzne reacts with formaldehyde and dry ...

Benzne reacts with formaldehyde and dry `HCl` gas in the precence of anhdous `ZnCl_(2)` to form

A

benzotrichloride

B

benzal chloride

C

benzyl chloride

D

benzoyl chloride

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To solve the question regarding the reaction of benzene with formaldehyde and dry HCl in the presence of anhydrous ZnCl2, we can follow these steps: ### Step 1: Identify the Reactants The reactants in this reaction are: - Benzene (C6H6) - Formaldehyde (HCHO) - Dry HCl (hydrochloric acid) - Anhydrous ZnCl2 (zinc chloride) ### Step 2: Understand the Role of ZnCl2 Anhydrous ZnCl2 acts as a Lewis acid catalyst. It helps in the generation of the electrophile from formaldehyde and HCl. ### Step 3: Formation of the Electrophile When formaldehyde reacts with dry HCl in the presence of ZnCl2, it forms a chloromethyl cation (CH2Cl+). The reaction can be summarized as follows: - HCHO + HCl → CH2Cl+ + ZnCl2 → CH2Cl+ + ZnO ### Step 4: Electrophilic Substitution Reaction The generated chloromethyl cation (CH2Cl+) is a strong electrophile. Benzene, being rich in electrons, can undergo electrophilic substitution with this cation. The reaction can be represented as: - C6H6 + CH2Cl+ → C6H5CH2Cl (Benzyl chloride) ### Step 5: Final Product The final product of the reaction is benzyl chloride (C6H5CH2Cl). ### Conclusion Thus, when benzene reacts with formaldehyde and dry HCl in the presence of anhydrous ZnCl2, the product formed is benzyl chloride.

To solve the question regarding the reaction of benzene with formaldehyde and dry HCl in the presence of anhydrous ZnCl2, we can follow these steps: ### Step 1: Identify the Reactants The reactants in this reaction are: - Benzene (C6H6) - Formaldehyde (HCHO) - Dry HCl (hydrochloric acid) - Anhydrous ZnCl2 (zinc chloride) ...
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