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The melting and boiling points of alkali...

The melting and boiling points of alkali metal halides always follow the trend ,

A

Iodide gt bromide gt chloride gt fluoride

B

Bromide gt chloride gt iodide gt fluoride

C

Fluoride gt chloride gt bromide gt iodide

D

Chloride gt fluoride gt bromide gt iodide

Text Solution

Verified by Experts

The correct Answer is:
C

For the same alkali metal ion, the lattice enthalpies decrease as the size of the halide ion increases. As the lattice enthalpies decrease, energy required to break the lattice (melting point) decreases and, hence, the melting points of alkali metal halides decrease from fluoride to iodide.
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R SHARMA-THE S BLOCK ELEMENTS-Follow-up Test 4
  1. Which of the following is correct for monoxides (normal oxides) of alk...

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  2. On combustion in excess ofd air, lithium forms

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  3. Which of the following in incorrect for the hydroxides of alkali metal...

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  4. All alkali metal peroxides contain the [-O-O]^(2-) ion. They are

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  5. All alkali metal superoxides contain the ion [O(2)]. They are

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  6. The alkali metal halides (MX) are all high melting, colorless crystall...

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  7. Alkali metal halides have high negative enthalpies of formation. The D...

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  8. The magnitude of enthalphy of formation of alkali metal halides decrea...

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  9. Which of the following is soluble in organic solvents like ethanol ?

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  10. Which of the following has the maximum melting point but minimum solub...

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  11. Which of the following is the correct order of hyrated ionic radii ?

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  12. Which of the following compounds is almost insoluble in water ?

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  13. The melting and boiling points of alkali metal halides always follow t...

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  14. Which of the following are oxosalts ? (i) Carbonates , (ii) Nitrates...

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  15. Which of the following is nott true?

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  16. Which of the following alkali metal carbonates doesnot existin the sol...

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  17. Sodium bicarbonate (NaHCO(3)) on gentle heting produces

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  18. Which of the following has the maximum solubility in water?

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