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Which of the following hydroxides of gro...

Which of the following hydroxides of group 2 elements is amphoteric ?

A

`Mg(OH)_(2)`

B

`Ca(OH)_(2)`

C

`Be(OH)_(2)`

D

`Sr(OH)_(2)`

Text Solution

Verified by Experts

The correct Answer is:
C

the basic strength of metl hydroxides is decided by the ease with which they can release `OH^(-)` ions. As we move down the group the attraction between `M^(2+)` ion and `OH^(-)` ions decreases on account of the decrease of change density of `M^(2+)` ion. therefore, the basic strength of group 2 hydroxides increases on moving down the group. Group 2 hydroxides are less basic than the corresponding group 1 hydroxides bacause `M^(2+)` ios with greater charge density attract `OH^(-)` ions
Strongly in comparison to `M^(+)` ions of alkali metals. `Be(OH)_(2)` is insoluble in water but dissolves in acid as well as in solutions containing an excess of `OH^(-)` ions
`Be(OH)_(2)+2HCl toBeCl_(2)+2H_(2)O`
`Be(OH)_(2)+2NaOHtoNa_(2)BeO_(2).2H_(2)O` or `Na_(2)[Be(OH)_(4)]`
or `Be(OH)_(2)+2OH^(-)tounderset("Beryllate ion")([Be(OH)_(4)]^(2-))`
`Be(OH)_(2)` is therefore, amphoteric.
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R SHARMA-THE S BLOCK ELEMENTS-Follow-up Test 10
  1. The hydroxide of is obtained by treating the metal with cold water.

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  2. Which of the following hydroxides is the most soluble in water ?

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  3. Which of the following hydroxides of group 2 elements is amphoteric ?

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  4. The most thermally stable hydroxide is

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  5. Which of the following halides are ionic in nature ?

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  6. All the halides of group 2 elements form hydrates and are hygroscopic ...

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  7. When hydrated MgCI(2).6H(2)O is trongly heated,

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  8. The hydrated halides of cannot be dehydrated on heating.

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  9. Fused BeF(2) is

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  10. Which of the following compounds is highly soluble in water ?

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  11. Which of the following compounds are water soluble ?

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  12. Which of the following solids is polymeric ?

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  13. Beryllium chloride vapor contains

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  14. Because it is cheap (a byproduct of the Solvay process) and deliquesce...

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  15. Which of the following is incorrect about the carbonates of alkaline e...

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  16. Which of the following carbonates is the least soluble in water ?

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  17. Which of the following carbonates is the most thermally stable ?

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  18. Which of the following bicarbonates exists in the solid state ?

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  19. Sulphates of group 2 metals are prepared by the action of sulphuric ac...

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  20. Which of the following sulphates crystallizes without water of crystal...

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