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Beryllium, the first member of group 2, ...

Beryllium, the first member of group 2, shows an anomalous behavior as compared to Mg and the rest of the members on account of

A

exceptionally small atomic and ionic radii

B

high ionization enthalpy

C

absence of vacant d-orbitals in its valence shell

D

all of these

Text Solution

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The correct Answer is:
D

Because of high ionization (due to small atomic radius) and high charge density (due to small ionic radius), Be forms covalent compounds in the anhydrous state which are easily hydrolysed. Due to the absence of vacant d-orbitals, Be dows not exhibit coordination number more that four while other members of group 2 can have a coordination number of six by using the vacant d-orbitals in their valence shell.
`[Be(H_(2)O)_(4)]Cl_(2)` and `[Ca(H_(2)O)_(6)]Cl_(2)`
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R SHARMA-THE S BLOCK ELEMENTS-Follow-up Test 11
  1. Which of the following group 2 elements forms a basic nitrate in addit...

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  2. Beryllium, the first member of group 2, shows an anomalous behavior as...

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  3. Beryllium shows a diagonal relationship with

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  4. Which of the following is incorrect for both B and AI?

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  5. Calcium oxide is called quick lime. It is prepared by the thermal deco...

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  6. Quick lime is prepared on a commercial scale by heating in a rotary k...

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  7. Which of the following is incorrect for quick lime ?

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  8. The addition of limited amount of water disintegrates the hard lumps o...

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  9. Soda lime is a mixture of

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  10. Lime is used for

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  11. Calcium hydroxide is called slaked lime. It is prepared on a commercia...

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  12. Which of the following is incorrect for slaked lime ?

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  13. A suspension of slaked lime in water is called

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  14. Bleaching powder is prepared by passing chlorine into

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  15. Which of the following changes occur when an excess of CO(2)(g) is pas...

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  16. Limestone rock is the commonest form of calcium carbonate which also o...

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  17. Calcium carbonate, commonly called limestone, is prepared by passing C...

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  18. Which of the following in incorrect for CaCO(3) ?

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  19. Calcium carbonate along with is used as a flux in the extraction of m...

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  20. Calcium carbonate is used as (i) a filler in cosmetics (ii) a cons...

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