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What is the reaction occuring at the ano...

What is the reaction occuring at the anode in Down's process for the extraction of sodium ?

A

`4OH^(-)rarr2H_(O)+O_(2)+4e^(-)`

B

`Na^(+)+e^(-)rarrNa`

C

`2Cl^(-)rarrCl_(2)+2e^(-)`

D

`NaOHrarrNa^(+)+OH^(-)`

Text Solution

Verified by Experts

The correct Answer is:
C

Now-a-days, Na metal is extracted by Down's process. It involves the electrolysis of fused sodium chloride containing `CaCl_(2)` and KF using Fe as cathode and graphite as anode at about `600^(@)`C, the melting point of the mixture:
At anode
`2Cl^(-)-2e^(-)rarrCl_(2)`
At cathode
`2Na^(+)+2e^(-)rarr2Na`
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