Which of the following is incorrect for cis-but-`2`-ene relative to trans-but-`2`-ene?
A
It has higher dipole moment.
B
It has higher boiling point.
C
It has higher melting point.
D
All of these
Text Solution
AI Generated Solution
The correct Answer is:
To determine which statement is incorrect for cis-but-2-ene relative to trans-but-2-ene, we need to analyze the properties of both isomers based on their molecular structure and how this affects their physical properties.
### Step-by-Step Solution:
1. **Identify the Structure of the Isomers**:
- **Cis-but-2-ene**: In this isomer, the two methyl groups (CH₃) are on the same side of the double bond.
- **Trans-but-2-ene**: In this isomer, the two methyl groups are on opposite sides of the double bond.
2. **Dipole Moment Comparison**:
- **Cis-but-2-ene** has a dipole moment because the two methyl groups on the same side create an uneven distribution of charge.
- **Trans-but-2-ene** has a dipole moment of zero because the dipoles from the two methyl groups cancel each other out due to their opposite positions.
3. **Boiling Point Comparison**:
- The presence of a dipole moment in **cis-but-2-ene** leads to stronger intermolecular attractions (dipole-dipole interactions), resulting in a higher boiling point compared to **trans-but-2-ene**.
4. **Melting Point Comparison**:
- The packing efficiency of molecules affects their melting points. **Trans-but-2-ene** can pack more efficiently in a crystal lattice due to its symmetrical structure, leading to a higher melting point.
- **Cis-but-2-ene**, being less symmetrical, does not pack as well, resulting in a lower melting point.
5. **Conclusion**:
- Based on the analysis:
- **Cis-but-2-ene has a higher boiling point than trans-but-2-ene** (True).
- **Cis-but-2-ene has a dipole moment, while trans-but-2-ene does not** (True).
- **Cis-but-2-ene has a higher melting point than trans-but-2-ene** (False).
Thus, the incorrect statement is that **cis-but-2-ene has a higher melting point than trans-but-2-ene**.
To determine which statement is incorrect for cis-but-2-ene relative to trans-but-2-ene, we need to analyze the properties of both isomers based on their molecular structure and how this affects their physical properties.
### Step-by-Step Solution:
1. **Identify the Structure of the Isomers**:
- **Cis-but-2-ene**: In this isomer, the two methyl groups (CH₃) are on the same side of the double bond.
- **Trans-but-2-ene**: In this isomer, the two methyl groups are on opposite sides of the double bond.
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