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Which of the following is incorrect for ...

Which of the following is incorrect for cis-but-`2`-ene relative to trans-but-`2`-ene?

A

It has higher dipole moment.

B

It has higher boiling point.

C

It has higher melting point.

D

All of these

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statement is incorrect for cis-but-2-ene relative to trans-but-2-ene, we need to analyze the properties of both isomers based on their molecular structure and how this affects their physical properties. ### Step-by-Step Solution: 1. **Identify the Structure of the Isomers**: - **Cis-but-2-ene**: In this isomer, the two methyl groups (CH₃) are on the same side of the double bond. - **Trans-but-2-ene**: In this isomer, the two methyl groups are on opposite sides of the double bond. 2. **Dipole Moment Comparison**: - **Cis-but-2-ene** has a dipole moment because the two methyl groups on the same side create an uneven distribution of charge. - **Trans-but-2-ene** has a dipole moment of zero because the dipoles from the two methyl groups cancel each other out due to their opposite positions. 3. **Boiling Point Comparison**: - The presence of a dipole moment in **cis-but-2-ene** leads to stronger intermolecular attractions (dipole-dipole interactions), resulting in a higher boiling point compared to **trans-but-2-ene**. 4. **Melting Point Comparison**: - The packing efficiency of molecules affects their melting points. **Trans-but-2-ene** can pack more efficiently in a crystal lattice due to its symmetrical structure, leading to a higher melting point. - **Cis-but-2-ene**, being less symmetrical, does not pack as well, resulting in a lower melting point. 5. **Conclusion**: - Based on the analysis: - **Cis-but-2-ene has a higher boiling point than trans-but-2-ene** (True). - **Cis-but-2-ene has a dipole moment, while trans-but-2-ene does not** (True). - **Cis-but-2-ene has a higher melting point than trans-but-2-ene** (False). Thus, the incorrect statement is that **cis-but-2-ene has a higher melting point than trans-but-2-ene**.

To determine which statement is incorrect for cis-but-2-ene relative to trans-but-2-ene, we need to analyze the properties of both isomers based on their molecular structure and how this affects their physical properties. ### Step-by-Step Solution: 1. **Identify the Structure of the Isomers**: - **Cis-but-2-ene**: In this isomer, the two methyl groups (CH₃) are on the same side of the double bond. - **Trans-but-2-ene**: In this isomer, the two methyl groups are on opposite sides of the double bond. ...
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