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The number of sigma and pi- bonds in alk...

The number of `sigma and pi`- bonds in alkyl isocyanide are

A

`9 sigma, 3pi`

B

`9 sigma, 9 pi`

C

`3 sigma, 4pi`

D

`5 sigma, 7pi`

Text Solution

Verified by Experts

The correct Answer is:
A

Isocyanides have the structure
`R-Noverset(rarr)=C:`
Allyl group is `CH_(2)=CH-CH_(2)-`
Thus, allyl isocyanide is
`H-underset(H)underset(|)C=underset(H)underset(|)C-underset(H)underset(|)overset(H)overset(|)C-Noverset(rarr)=C`
Every single bond is `sigma` bond, double bond contains one `sigma` and one `pi` bond, and triple bond contains one `sigma` and two `pi` bonds. Thus, the total number of `sigma` bonds is `9` and the total number of `pi` bonds is `3`.
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