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The edge length of face centred cubic un...

The edge length of face centred cubic unit cell is `5.8` pm. if the radius of the caiton is `110` pm. The radius of the anion is

A

`288` pm

B

`398` pm

C

`144` pm

D

`618` pm

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The correct Answer is:
3

Imagine `NaCl` crystal which has fcc unit cell.The chloride ions are at the corners while sodium ion is at the edge centre thus.
edge length =`2r_(+)+2r_(-)=2(r_(+)+r_(-))`
`r_(+)+r_(-)=("Edge length")/(2)=(508p m)/(2)`
`=254p m`
Hence
`r_(-)=254p m-r_(+)`
`=(254p m)-(110p m)`
`=144p m`
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