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The Ca^(2+) and F^(-) ions arc located i...

The `Ca^(2+)` and `F^(-)` ions arc located in `CaF_(2)` crystal respectively at face centred cubic lattice points and in

A

tetrahedral voids

B

half of tetrahedral voids

C

octahedral voids

D

half of octahedral voids

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The correct Answer is:
1

The `Ca^(2+)` ions from a face centered cubic arrangement .The `Ca^(2+)` ions are too small to touch each other ,so the structure is not close packed. However the structure is releated to a close-packed arrangement since the `Ca^(2+)` ions occupy the same relative positions as for a cubic close -packed structure and the `F^(-)` ions occupy all the tetrahedral voids.
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