Home
Class 12
CHEMISTRY
Standard reduction potentails of the hal...

Standard reduction potentails of the half reactions are given below:
`F_(2)(g)+2e^(-) rarr 2F^(-)(aq.),, E^(ɵ)= +2.87`
`Cl_(2)(g)+2e^(-) rarr 2Cl^(-)(aq.),, E^(ɵ)= +1.36 V`
`Br_(2)(g)+2e^(-) rarr 2Br^(-)(aq.),, E^(ɵ)= +1.09 V`
`I_(2)(s)+2e^(-) rarr 2l^(-)(aq.),, E^(ɵ)= +0.54 V`
The strongest oxidizing and reducing agents respectively are:

A

`Cl_(2)` and `I_(2)`

B

`F_(2)` and `I^(-)`

C

`Br_(2)` and `Cl^(-)`

D

`Cl_(2)` and `Br^(-)`

Text Solution

Verified by Experts

The correct Answer is:
B

Oxidizing agent oxidizes the other substance and gets oxidized. Therefore, strongest reducing agent has the lowest reduction potenital but highest oxidation potential:
`F_(2)(g)+2e^(-)rarr2F^(-)(aq.),E^(Theta) = +2.87V`
Reducting agent reduces the other substance and gets oxidized. Therefore, strongest reducing agent has the lowest reduction potential but highest oxidatiuon potential :
`2I^(-)(aq.)rarr 2e^(-)+I_(2)(s),E^(Theta) = -0.54 V`
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    R SHARMA|Exercise Follow-up Test 1|3 Videos
  • ELECTROCHEMISTRY

    R SHARMA|Exercise Follow-up Test 2|6 Videos
  • ELECTROCHEMISTRY

    R SHARMA|Exercise Question Bank [Building the Knowledge Level IV]|3 Videos
  • COORDINATION COMPOUNDS

    R SHARMA|Exercise Archives|56 Videos
  • GENERAL PRINCIPALS AND ISOLATION OF ELEMENTS

    R SHARMA|Exercise Arechives|16 Videos

Similar Questions

Explore conceptually related problems

Standard reduction potentials of the half reactions are given below {:(F_(2(g))+2e^(-) rarr 2F^(-)""_((aq)),,E^(@)=+2.85V), (Cl_(2(g))+2e^(-) rarr 2Cl^(-)""_((aq)),, E^(@)=+1.36V), (Br_(2(l))+2e^(-) rarr 2Br^(-)""_((aq)),,E^(@)=+1.06V), (l_(2(s))+2e^(-) rarr 2l^(-)""_((aq)),, E^(@)=+0.53V):} The strongest oxidising and reducing agents respectively are

Standrd reduction potentials of the half reactions are given below : F_2 (g) +re^- rarr 2 F^(-) (aq) E^@ = + 2.85 V Cl_2 (g) +2e^- rarr 2 Cl^-(aq) , E^2 = + 1.36 V Br _2 (i) + 2 e^- rarr 2Br (aq) , E^2 = + 1. 06 V I_2 (s) + 2 e^- rarr 2I^(-) (aq) , E^2 = + . 53 V . The strongest oxidizing and reducing agents respectively

R SHARMA-ELECTROCHEMISTRY-Archives
  1. The Gibbs energy for the decomposition of Al(2)O(3) at 500^(@)C is as...

    Text Solution

    |

  2. Molar conductivities (Lambda(m)^(@)) at infinite dilution of NaCl, HCl...

    Text Solution

    |

  3. Standard reduction potentails of the half reactions are given below: ...

    Text Solution

    |

  4. The electrotrode potentials for Cu^(2+)(aq.)+2e^(-) rarr Cu^(+)(aq.)...

    Text Solution

    |

  5. Standard electrode potential for Sn^(4+)//Sn^(2+) couple is 0.15 V and...

    Text Solution

    |

  6. Standard electrode potential of three metal X, Y and Z are -1.2 V, +0....

    Text Solution

    |

  7. A solution contains Fe^(2+), Fe^(3+) and T^(-) ions. This solution was...

    Text Solution

    |

  8. An increase in equivalent conductance of a strong electrolyte with dil...

    Text Solution

    |

  9. For the reduction of silver ions with copper metal, the standard cell ...

    Text Solution

    |

  10. Which of the following expressions correctly represents the equivalent...

    Text Solution

    |

  11. Consider the following relations for emf of a electrochemical cell (...

    Text Solution

    |

  12. Given: (i) Cu^(2+)+2e^(-) rarr Cu, E^(@) = 0.337 V (ii) Cu^(2+)+e^...

    Text Solution

    |

  13. Al(2)O(3) is reduced by electrolysis at low potentials and high curren...

    Text Solution

    |

  14. The equivalent conductance of M//32 solution of a weak monobasic acid ...

    Text Solution

    |

  15. Kohlrausch s law states that at :

    Text Solution

    |

  16. On the basis of the following E^(@) values, the stongest oxidizing age...

    Text Solution

    |

  17. The efficiency of a fuel cell is given by:

    Text Solution

    |

  18. Calculate the equilibrium constant for the reaction Cu(s)+2Ag^(+)(aq)r...

    Text Solution

    |

  19. If E(Fe^(2+))^(@)//Fe = -0.441 V and E(Fe^(3+))^(@)//Fe^(2+) = -0.77...

    Text Solution

    |

  20. A hypothetical elecrochemical cell is shown below: A^(ɵ)|A^(+)(xM)||...

    Text Solution

    |