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A hypothetical elecrochemical cell is sh...

A hypothetical elecrochemical cell is shown below:
`A^(ɵ)|A^(+)(xM)||B^(+)(yM)||B^(o+)`
The emf measured is `+0.20 V`. The cell reaction is

A

`A+B^(+) rarr A^(+)+B`

B

`A^(+)+B rarr A+B^(+)`

C

`A^(+)+e^(-) rarr A, B^(+)+e^(-) rarr B`

D

The cell reaction can't be predicated

Text Solution

Verified by Experts

The correct Answer is:
A

Since the emf of the hypothetical electrochemical cell is positive `(+0.20 V)`, the choice of electrodes as mentioned in the convention is correct. Thus Anode reaction (oxid):
`A rarr A^(+)+e^(-)`
Cathode reaction (Redu):
`B^(+)+e^(-) rarr B`
Cell reaction
`A+B^(+) rarr A^(+)+B, E_("cell")^(@) = +0.20 V`
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