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Which of the following is a hexadentate ...

Which of the following is a hexadentate ligand ?

A

Ethylenediaminetetraacetato

B

Dimethylglyoxime anion

C

8- Hydroxyquinolinol ion

D

2,2' - Dipyridyl

Text Solution

Verified by Experts

The correct Answer is:
A

Ethylene diamineteracetate ion, `(EDTA)^(4-)` , is a ligand that bonds through six of its atoms. It bonds through two N atom and four O atoms to the metal and so forms five rings. Because of the stabilitity of chelates, polydentate ligands (aso called chelating agents) are often used to remove metal ions form a chemical system. For example, EDTA is added to certin canned foods to remove transition-metal ions that can catalyze the ddeterioration of the food. The same chelating agent has been used to treat lead poisoning because it binds `Pb^(2+)` ions as the chelat, which can then be excreated by the kidneys.
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