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Which one of the following conformations...

Which one of the following conformations of cyclohexane is chiral?

A

Chiral

B

Twist boat

C

Boat

D

Rigid

Text Solution

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The correct Answer is:
To determine which conformation of cyclohexane is chiral, we need to analyze the symmetry of the different conformations of cyclohexane. Here’s a step-by-step solution: ### Step 1: Understand Chirality Chirality refers to a molecule that cannot be superimposed on its mirror image. For a molecule to be chiral, it must lack a plane of symmetry. **Hint:** Remember that chiral molecules have non-superimposable mirror images. ### Step 2: Identify Cyclohexane Conformations Cyclohexane can adopt several conformations, including: - Chair conformation - Boat conformation - Twist-boat conformation **Hint:** Familiarize yourself with the different conformations of cyclohexane and their structures. ### Step 3: Analyze the Chair Conformation The chair conformation of cyclohexane is the most stable and has a symmetrical structure. It can be divided into two halves that are mirror images of each other, indicating that it has a plane of symmetry. **Hint:** Visualize the chair conformation and look for symmetry. ### Step 4: Analyze the Boat Conformation The boat conformation also has a plane of symmetry. The two ends of the boat can be seen as mirror images, which means it is not chiral. **Hint:** Check for symmetry in the boat conformation as well. ### Step 5: Analyze the Twist-Boat Conformation The twist-boat conformation does not have a plane of symmetry. The arrangement of atoms in this conformation is such that it cannot be superimposed on its mirror image, making it chiral. **Hint:** Look closely at the twist-boat structure and see if you can find any symmetry. ### Step 6: Conclusion Among the conformations of cyclohexane, the twist-boat conformation is the only one that is chiral, as it lacks a plane of symmetry. **Final Answer:** The twist-boat conformation of cyclohexane is chiral.

To determine which conformation of cyclohexane is chiral, we need to analyze the symmetry of the different conformations of cyclohexane. Here’s a step-by-step solution: ### Step 1: Understand Chirality Chirality refers to a molecule that cannot be superimposed on its mirror image. For a molecule to be chiral, it must lack a plane of symmetry. **Hint:** Remember that chiral molecules have non-superimposable mirror images. ### Step 2: Identify Cyclohexane Conformations ...
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Knowledge Check

  • Which one of the following conformation of cyclohexane is chiral

    A
    Twist boat
    B
    Rigid
    C
    Chair
    D
    Boat
  • Which one of the follwing conformations of cyclohexane is chiral ?

    A
    Boat
    B
    Twist boat
    C
    Rigid
    D
    Chair
  • Which one of the following conformations of cyclohexane is the least stable ?

    A
    Half - chair
    B
    Boat
    C
    Twisted - boat
    D
    Chair
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