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In the reaction CH(3)CHO+HCNrarrCH(3...

In the reaction
`CH_(3)CHO+HCNrarrCH_(3)CH(OH)CNoverset(H_(2)O)rarrCH_(3)CH(OH)COOH`
an asymmertic cabron is generated. The acid obtained would be

A

`D-`isomer

B

`L-`isomer

C

`50%D` and `50%L` isomer

D

`20%D` and `80%L` isomer

Text Solution

Verified by Experts

The correct Answer is:
C

Synthesis fo a chiral compound, `CH_(3)CH(OH)CN`, from achiral reactants, `CH_(3)CHO` and `CN^(-)`, always yields the racemic modification.

The flat aldehyde is said to have enatiopic faces because attachement of a fiurth ligands to one or the other face gives one or the other enantiomer. These attacks occur with equal probability, resulting in equal amounts of `D` and `L` (a racemic mixture).
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