Monosaccharides are assigned `D-` or `L` configuration depending upon whether its standard. Fischer projection formula has a right or left orientation respectively of the hydroxyl group at the
Monosaccharides are assigned `D-` or `L` configuration depending upon whether its standard. Fischer projection formula has a right or left orientation respectively of the hydroxyl group at the
A
anomeric carbon
B
carbon 2
C
topmost asymmetric carbon atom
D
bottommost asymmetric carbon atom
Text Solution
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The correct Answer is:
D
All the naturally occurring monosaccharides belong to the D-Series because in the Fischer projection, the `OH` group at their respective penultimate carbon atom (or the last chiral carbon atom) is oriented towards right as in `D - (+) -` glyceraldehyde.
Synthetic sugars may have either `D -` or `L-` series. In `L-` series, the `OH` group on the penultimate carbon atom (or the last chiral carbon atom) is oriented toward left as in `L - (-) -` glyceraldehyde.
Synthetic sugars may have either `D -` or `L-` series. In `L-` series, the `OH` group on the penultimate carbon atom (or the last chiral carbon atom) is oriented toward left as in `L - (-) -` glyceraldehyde.
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Monosaccharides are polyhydric aldehydes and ketones which cannot be hydrolysed into simpler carbohydrates. The monosaccharides containing -CHO group are called aldoses while those containing C=O group are called ketoses. The aldehyde group is always present at C_(1) while keto group is generally present at C_(2) . All monosaccharides are oxidised by Tollen's reagent and Fehling solution and are called reducing sugars. The monosaccharide molecules may be assigned D and L-configurations depending upon whether the configuration of the molecule is related to D- or L-glyceraldehyde. If the -OH group is attached to the carbon adjacent to the -CH_(2)OH group (last chiral carbon) is on the right hand side, it is assigned D-configuration. The molecule is assigned L-configuration if the -OH group attached to the carbon adjacent to the -CH_(2)OH group is on the left. The monosaccharides contain one or more chiral carbon atoms. Pentoses and hexoses have cyclic structures furanose (five membered) and pyranose (six membered). During cyclization, C_(1) in aldohexoses and C_(2) in fructose become chiral and the newly formed -OH group may be either on the left or on the right in Fischer projection formulae. These monosaccharides, therefore, exist in two stereoisomeric forms called alpha -anomer and beta -anomer while C_(1) and C_(2) are called glycosidic or anomeric carbon. The bonds joining glycosidic carbon are called glycosidic linkages. D(+) glucose exists in two stereoisomeric forms, alpha -D- glucose and beta -D-glucose. When either of these two forms of glucose i.e., alpha-D- glucose are dissolved in water and allowed to stand, these get slowly converted into other form and an equilibrium mixture of both is formed. This process is called mutarotation. Two forms of D-glucopyranose are called
Monosaccharides are polyhydric aldehydes and ketones which cannot be hydrolysed into simpler carbohydrates. The monosaccharides containing -CHO group are called aldoses while those containing C=O group are called ketoses. The aldehyde group is always present at C_(1) while keto group is generally present at C_(2) . All monosaccharides are oxidised by Tollen's reagent and Fehling solution and are called reducing sugars. The monosaccharide molecules may be assigned D and L-configurations depending upon whether the configuration of the molecule is related to D- or L-glyceraldehyde. If the -OH group is attached to the carbon adjacent to the -CH_(2)OH group (last chiral carbon) is on the right hand side, it is assigned D-configuration. The molecule is assigned L-configuration if the -OH group attached to the carbon adjacent to the -CH_(2)OH group is on the left. The monosaccharides contain one or more chiral carbon atoms. Pentoses and hexoses have cyclic structures furanose (five membered) and pyranose (six membered). During cyclization, C_(1) in aldohexoses and C_(2) in fructose become chiral and the newly formed -OH group may be either on the left or on the right in Fischer projection formulae. These monosaccharides, therefore, exist in two stereoisomeric forms called alpha -anomer and beta -anomer while C_(1) and C_(2) are called glycosidic or anomeric carbon. The bonds joining glycosidic carbon are called glycosidic linkages. D(+) glucose exists in two stereoisomeric forms, alpha -D- glucose and beta -D-glucose. When either of these two forms of glucose i.e., alpha-D- glucose are dissolved in water and allowed to stand, these get slowly converted into other form and an equilibrium mixture of both is formed. This process is called mutarotation. The maximum number of optical isomers of glucose expected are
Monosaccharides are polyhydric aldehydes and ketones which cannot be hydrolysed into simpler carbohydrates. The monosaccharides containing -CHO group are called aldoses while those containing C=O group are called ketoses. The aldehyde group is always present at C_(1) while keto group is generally present at C_(2) . All monosaccharides are oxidised by Tollen's reagent and Fehling solution and are called reducing sugars. The monosaccharide molecules may be assigned D and L-configurations depending upon whether the configuration of the molecule is related to D- or L-glyceraldehyde. If the -OH group is attached to the carbon adjacent to the -CH_(2)OH group (last chiral carbon) is on the right hand side, it is assigned D-configuration. The molecule is assigned L-configuration if the -OH group attached to the carbon adjacent to the -CH_(2)OH group is on the left. The monosaccharides contain one or more chiral carbon atoms. Pentoses and hexoses have cyclic structures furanose (five membered) and pyranose (six membered). During cyclization, C_(1) in aldohexoses and C_(2) in fructose become chiral and the newly formed -OH group may be either on the left or on the right in Fischer projection formulae. These monosaccharides, therefore, exist in two stereoisomeric forms called alpha -anomer and beta -anomer while C_(1) and C_(2) are called glycosidic or anomeric carbon. The bonds joining glycosidic carbon are called glycosidic linkages. D(+) glucose exists in two stereoisomeric forms, alpha -D- glucose and beta -D-glucose. When either of these two forms of glucose i.e., alpha-D- glucose are dissolved in water and allowed to stand, these get slowly converted into other form and an equilibrium mixture of both is formed. This process is called mutarotation. Which of the following statements is not correct?
Monosaccharides are polyhydric aldehydes and ketones which cannot be hydrolysed into simpler carbohydrates. The monosaccharides containing -CHO group are called aldoses while those containing C=O group are called ketoses. The aldehyde group is always present at C_(1) while keto group is generally present at C_(2) . All monosaccharides are oxidised by Tollen's reagent and Fehling solution and are called reducing sugars. The monosaccharide molecules may be assigned D and L-configurations depending upon whether the configuration of the molecule is related to D- or L-glyceraldehyde. If the -OH group is attached to the carbon adjacent to the -CH_(2)OH group (last chiral carbon) is on the right hand side, it is assigned D-configuration. The molecule is assigned L-configuration if the -OH group attached to the carbon adjacent to the -CH_(2)OH group is on the left. The monosaccharides contain one or more chiral carbon atoms. Pentoses and hexoses have cyclic structures furanose (five membered) and pyranose (six membered). During cyclization, C_(1) in aldohexoses and C_(2) in fructose become chiral and the newly formed -OH group may be either on the left or on the right in Fischer projection formulae. These monosaccharides, therefore, exist in two stereoisomeric forms called alpha -anomer and beta -anomer while C_(1) and C_(2) are called glycosidic or anomeric carbon. The bonds joining glycosidic carbon are called glycosidic linkages. D(+) glucose exists in two stereoisomeric forms, alpha -D- glucose and beta -D-glucose. When either of these two forms of glucose i.e., alpha-D- glucose are dissolved in water and allowed to stand, these get slowly converted into other form and an equilibrium mixture of both is formed. This process is called mutarotation. Mutarotation does not occur in
Monosaccharides are polyhydric aldehydes and ketones which cannot be hydrolysed into simpler carbohydrates. The monosaccharides containing -CHO group are called aldoses while those containing C=O group are called ketoses. The aldehyde group is always present at C_(1) while keto group is generally present at C_(2) . All monosaccharides are oxidised by Tollen's reagent and Fehling solution and are called reducing sugars. The monosaccharide molecules may be assigned D and L-configurations depending upon whether the configuration of the molecule is related to D- or L-glyceraldehyde. If the -OH group is attached to the carbon adjacent to the -CH_(2)OH group (last chiral carbon) is on the right hand side, it is assigned D-configuration. The molecule is assigned L-configuration if the -OH group attached to the carbon adjacent to the -CH_(2)OH group is on the left. The monosaccharides contain one or more chiral carbon atoms. Pentoses and hexoses have cyclic structures furanose (five membered) and pyranose (six membered). During cyclization, C_(1) in aldohexoses and C_(2) in fructose become chiral and the newly formed -OH group may be either on the left or on the right in Fischer projection formulae. These monosaccharides, therefore, exist in two stereoisomeric forms called alpha -anomer and beta -anomer while C_(1) and C_(2) are called glycosidic or anomeric carbon. The bonds joining glycosidic carbon are called glycosidic linkages. D(+) glucose exists in two stereoisomeric forms, alpha -D- glucose and beta -D-glucose. When either of these two forms of glucose i.e., alpha-D- glucose are dissolved in water and allowed to stand, these get slowly converted into other form and an equilibrium mixture of both is formed. This process is called mutarotation. Which of the following pairs give positive Tollen's test?
Carbohydrates play a vital role in our daily life. These are classified as monosacchrides, oligosaccharides and polysaccharides depending upon the number of smaller molecules on hydrolysis. It has been suggested that monosaccharides do not have a free aldehyde or ketonic group but have cyclic hemiacetal or hemiketal structures. D - Glucose exists in two isomeric stereoisomeric forms : alpha-D- glucose and beta-D glucose which have different positions of H and OH groups on first carbon atom. Disaccharides such as sucuose, maltose, lactose, etc., give monosaccharides on hydrolysis. Polysaccharides are starch, cellulose, glycogen, having molecular formula (C_(6)H_(10)O_(5))_(n) . Name the water insoluble component of starch.
Carbohydrates play a vital role in our daily life. These are classified as monosacchrides, oligosaccharides and polysaccharides depending upon the number of smaller molecules on hydrolysis. It has been suggested that monosaccharides do not have a free aldehyde or ketonic group but have cyclic hemiacetal or hemiketal structures. D - Glucose exists in two isomeric stereoisomeric forms : alpha-D- glucose and beta-D glucose which have different positions of H and OH groups on first carbon atom. Disaccharides such as sucuose, maltose, lactose, etc., give monosaccharides on hydrolysis. Polysaccharides are starch, cellulose, glycogen, having molecular formula (C_(6)H_(10)O_(5))_(n) . What is the name of the linkage which holds together monosaccharide units in sucrose?
In the modern periodic table, elements are arranged in order of increasing atomic numbers, which is related to the electornic configuration. Depending upon the type of orbitals receiving the last electron, the elements in the periodic table have been divided into four blocks, viz, p,d and f. The modern periodic table consists of 7 periods and 18 groups. Each period begins with the filling of a new energy shell. in accordance with the Aufbau principal, the seven periods (1 to 7) have 2,8,8,18,18,32 and 32 elements respectively. The seventh period is still incomplete. To avoid the periodic table being too long, the two series of f-block elements, called lanthanoids and actinoids, are placed at the bottom of the main body of the periodic table The electronic configuration of the element which is just above the element with atomic number 43 in the same group is
In the modern periodic table, elements are arranged in order of increasing atomic numbers, which is related to the electornic configuration. Depending upon the type of orbitals receiving the last electron, the elements in the periodic table have been divided into four blocks, viz, p,d and f. The modern periodic table consists of 7 periods and 18 groups. Each period begins with the filling of a new energy shell. in accordance with the Aufbau principal, the seven periods (1 to 7) have 2,8,8,18,18,32 and 32 elements respectively. The seventh period is still incomplete. To avoid the periodic table being too long, the two series of f-block elements, called lanthanoids and actinoids, are placed at the bottom of the main body of the periodic table The last element of the p-block in 6th period is represented by the outermost electronic configuration
In the modern periodic table, elements are arranged in order of increasing atomic numbers, which is related to the electornic configuration. Depending upon the type of orbitals receiving the last electron, the elements in the periodic table have been divided into four blocks, viz, p,d and f. The modern periodic table consists of 7 periods and 18 groups. Each period begins with the filling of a new energy shell. in accordance with the Aufbau principal, the seven periods (1 to 7) have 2,8,8,18,18,32 and 32 elements respectively. The seventh period is still incomplete. To avoid the periodic table being too long, the two series of f-block elements, called lanthanoids and actinoids, are placed at the bottom of the main body of the periodic table The element with atomic number 57 belongs to
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