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Which one is the most acidic compound?...

Which one is the most acidic compound?

A

B

C

D

Text Solution

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The correct Answer is:
C

Electron-withdrawing gourps `(EWG)` like `-NO_(2)` which stablize the phenoxide ion further by dispersing the negative charge increase the acidic strength of phenols. On the other hand, electron-donating groups `(EDG)` like `CH_(3)` which destabilizes the phenoxide ion by intensifying the negative charges decrease the acidic strength of phenols Further, greater the number of electron - withdrawing groups at o-and p-positionsk, more acidic is the phenol. Thus, correct order of acidic strength is: `(3) gt (2) gt (1) gt (4)`
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