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Correct increasing order for the wavelen...

Correct increasing order for the wavelengths of absorption in the visible region by the complexes of `Co^(3+)` is:

A

`[Co(H_(2)O)_(6)]^(3+), [Co(en)_(3)]^(3+), [Co(NH_(3))_(6)]^(3+)`

B

`[Co(H_(2)O)_(6)]^(3+), [Co(NH_(3))_(6)]^(3+), [Co(en)_(3)]^(3+)`

C

`[Co(H_(2)O)_(6)]^(3+), [Co(en)_(3)]^(3+), [Co(H_(2)O)_(6)]^(3+)`

D

`[Co(en)_(3)]^(3+), [Co(NH)_(3))_(6)]^(3+), [Co(H_(2)O)_(6)]^(3+)`

Text Solution

Verified by Experts

The correct Answer is:
D

`Delta E prop` field of ligand strength `prop (1)/(lambda)`
correct order of field strength of ligand:
`H_(2) O lt NH_(3) lt en`
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