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The geometry and magnetic behaviour of t...

The geometry and magnetic behaviour of the complex `[Ni(CO)_4]` are

A

square planar geometry and diamagnetic

B

tetraheral geometry and diamgnetic

C

square planer geometry and paramagnetic

D

tetrahedral geometry and paramagnetic

Text Solution

Verified by Experts

The correct Answer is:
B

`[Ni (CO)_(4)] implies Ni (0) implies 3 d^(8) 4 s^(2)`
Since `CO` is a strong field ligand, the resulting electronic configuration is:
It is diamagnetic due to absence of unpaired electrons. It gemetry is tetrahedral as `sp^(3)` hybrid obitals are involved in bonding.

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