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Excess of Kl and dill. H(2)SO(4) were m...

Excess of Kl and dill. `H_(2)SO_(4)` were mixed in 50 mL `H_(2)O_(2)`. Thus, `l_(2)` liberated requires 20 mL of 0.1 N `Na_(2)S_(2)O_(3)`. What will be the strenght of `H_(2)O_(2)` in g `L^(-1)` ?

A

0.034

B

0.68

C

6.8

D

5.8

Text Solution

Verified by Experts

The correct Answer is:
B

For 20 mL of `H_(2)O_(2)`,
Meq of Kl = Meq. Of `H_(2)O_(2)` in 50 mL = Meq. Of `Na_(2)S_(2)O_(3)`
`(wxx1000)/(34//2)=20xx0.1`
`therefore W_(H_(2)O_(2))" in 50 mL"=(20xx0.1xx34)/(2000)=0.034`
`therefore W_(H_(2)O_(2))" in 1000 mL"=(0.034xx1000)/(50)=0.68g//L`
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50 mL of an aqueous solution of H_(2)O_(2) was treated with an excess of KI solution and dilute H_(2)SO_(4) . The liberated iodine required 20 mL 0.1 N Na_(2)S_(2)O_(3) solution for complete interaction. Calculate the concentration of H_(2)O_(2) in g//L .

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