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The molar conductivites wedge(NaOAc)^(@...

The molar conductivites `wedge_(NaOAc)^(@)` and `wedge_(HCI)^(W)` at infinite dilution in water at `25^(@)C` are 91.0 and 426.2 `cm^(2)//"mol"` respecitvely To calculate `wedge_(HoAc)^(@)` the additional value required is

A

`wedge_(H_(2)O)^(@)`

B

`wedge_(KCI)^(@)`

C

`wedge_(NaOH)`

D

`wedge_(NaCI)`

Text Solution

Verified by Experts

The correct Answer is:
C

According to kohlrausch 's law
`wedge_(CH_(3)COOH)^(@)=wedge_(CH_(3)COOH_(-))^(@) +wedge_(H^(+))^(@)`
`wedge_(HCI)^(@)=wedge_(H^(+))^(@) +wedge_(CI_(-))^(@)`
To calculate `wedge_("GOAC")^(@) =wedge_("HCI")+wedge_(NaOAC)^(@)-wedge_(NaCI)^(@)` thus additoinal value required is `wedge_(NaCI)^(@)`
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The molar conductivities Lambda_(NaOAc)^@ and Lambda_(HCI)^@ at infinite dilution is watter at 25^@C are 91.0 and 426.2 S cm^@ // mol respectively. To calculate Lambda_(HOAc,)^2 the additional value required is:

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