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Nernst equation for the reaction aA+bB...

Nernst equation for the reaction
`aA+bBoverset("ne"-)rarr cC+ dD` is
`E_(cell)=E_(cell)^(@)-(RT)/(nF) "ln" Q`
what is Q in the Nernst equation

A

`([A]^(a)[B]^(b))/([C]^(c )[D]^(d))`

B

`([A]^(a)[D]^(d))/([B]^(b )[C]^(C ))`

C

`([C]^(c )[D]^(d))/([A]^(a)[B]^(b))`

D

`([C ]^(c)[A]^(a))/([D]^(d)[B]^(b))`

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AI Generated Solution

The correct Answer is:
To solve the question about the Nernst equation and specifically what Q represents, we can break it down into the following steps: ### Step 1: Understand the Nernst Equation The Nernst equation is given as: \[ E_{cell} = E_{cell}^\circ - \frac{RT}{nF} \ln Q \] Where: - \( E_{cell} \) = cell potential under non-standard conditions - \( E_{cell}^\circ \) = standard cell potential - \( R \) = universal gas constant (8.314 J/(mol·K)) - \( T \) = temperature in Kelvin - \( n \) = number of moles of electrons transferred in the reaction - \( F \) = Faraday's constant (approximately 96485 C/mol) - \( Q \) = reaction quotient ### Step 2: Define the Reaction Quotient (Q) The reaction quotient \( Q \) is a measure of the relative amounts of products and reactants present in a reaction at any point in time. It is defined for a general reaction: \[ aA + bB \rightleftharpoons cC + dD \] as: \[ Q = \frac{[C]^c [D]^d}{[A]^a [B]^b} \] ### Step 3: Identify the Components of Q In the expression for \( Q \): - The concentrations of the products (C and D) are raised to the power of their coefficients in the balanced equation. - The concentrations of the reactants (A and B) are also raised to the power of their coefficients. - \( [C] \), \( [D] \), \( [A] \), and \( [B] \) represent the molar concentrations of the respective species. ### Step 4: Distinguish Between Q and K It is important to note that: - \( Q \) can be calculated at any point during the reaction, regardless of whether the system is at equilibrium. - When the system reaches equilibrium, \( Q \) becomes the equilibrium constant \( K \). ### Final Answer Thus, in the context of the Nernst equation, \( Q \) is the reaction quotient, which is calculated as: \[ Q = \frac{[C]^c [D]^d}{[A]^a [B]^b} \]

To solve the question about the Nernst equation and specifically what Q represents, we can break it down into the following steps: ### Step 1: Understand the Nernst Equation The Nernst equation is given as: \[ E_{cell} = E_{cell}^\circ - \frac{RT}{nF} \ln Q \] Where: - \( E_{cell} \) = cell potential under non-standard conditions - \( E_{cell}^\circ \) = standard cell potential ...
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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ELECTROCHEMISTRY-Exercise 2
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