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E(cell)^(@) for some half cell reaction ...

`E_(cell)^(@)` for some half cell reaction are given below on the basis of these mark the correct answer
`I H^(+)(aq)+e^(-)rarr1/2 H_(2)(g),E_(cell)^(-)=0.00 V`
II`2H_(2)O(l)rarrO_(2)(g)+4H^(+)(Aq)+4e^(-),E_(cell)^(-)=1.23 V`
III `2SO_(4)^(2-)(aq)rarrS_(2)O_(8)^(2-)(aq)+2e^(-)+2e^(-),E_(cell)^(-)=1.96 V`

A

in dilute suplhuric acid solution hydrogen will be reduced at cathode

B

in concentrated sulplhuric acid solution water will be oxidised at anode

C

in dilute sulphuric acid solution water will be oxidised at cathode

D

in dilute sulphuric acid solution `SO_(4)^(2-)` ion will be oxidised to tetrathionate ion anode

Text Solution

Verified by Experts

The correct Answer is:
D

In dilue `H_(2)SO_(4)` solution hydrogen will be reduced at cathode
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Potential for some half cell reactions are given below. On the basis of these mark the correct answer. (i) H^(+)(aq) + e^(-) rightarrow (1/2)H^(2)(g) E_(cell)^(@) = 0.00V (ii) 2H_(2)O(l) rightarrow O_(2)(g) + 4H^(+)(aq) + 4e^(-) , E_(cell) = 1.96V (iii) 2SO_(4)^(2-)(aq) rightarrow S_(2)O_(8)^(2-)(aq) + 2e^(-), E_(cell)^(@) = 1.96V

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MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-ELECTROCHEMISTRY-Exercise 2
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