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The electron -withdrawing group from...

The electron -withdrawing group from the following is _______.

A

`-CH_(3)`

B

`-CH_(2)CH_(3)`

C

`-C(CH_(3))_(3)`

D

`-SO_(3)H`

Text Solution

Verified by Experts

The correct Answer is:
D
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Assertion : p-nitroaniline is stronger base than p-toluidine . The electron withdrawing NO_(2) group in the p-nitroaniline makes it a stronger base .

Identify electron-donating groups in resonance among the following.

Assertion (A) Presence of a nitro group at ortho or para position increases the reactivity of haloarenas towards nucleophilic substitution. Reason (R ) Nitro group, being an electron withdrawing group decreases the electron density over the benzene ring.

Assertion: Presence of a nitro group at ortho or para position increases the reactivity of haloarenes towards nucleophilic substitution. Reason: Nitro group, being an electron withdrawing group decreases the electron density over the benzene ring.

Knowledge Check

  • Assertion : p-nitroaniline is stronger base than p-toluidine . The electron withdrawing NO_(2) group in the p-nitroaniline makes it a stronger base .

    A
    If both the assertion and reason are true statement and reason is correct explanation of the assertion .
    B
    If both the assertion and reason are true statement but reason is not a correct explanation of the assertion .
    C
    If the assertion is true but the reason is a false statement.
    D
    If both assertion and reason are false statements.

  • Electron donating groups are,

    A
    o-direction
    B
    p-directing
    C
    m-directing
    D
    o and p-directing

  • Identify electron-donating groups in resonance among the following.

    A
    `-CONH_(2)`
    B
    `-NO_(2)`
    C
    `-OCOCH_(3)`
    D
    `-NHCOCH_(3)`