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The product (D ) in the following s...

The product (D ) in the following sequence of reaction is
`CH_(3) COOH overset(NH_(3))(to) (A ) overset( " Heat ")(to) (B )`
`overset(P_(2)O_(5))(to) ( C ) overset(Na+ C_(2)H_(5) OH) (to) (D ) `

A

Ester

B

Amine

C

Acid

D

Alcohol

Text Solution

AI Generated Solution

The correct Answer is:
To determine the product (D) in the given sequence of reactions, we will analyze each step carefully. ### Step 1: Reaction of Acetic Acid with Ammonia - **Reaction**: CH₃COOH + NH₃ → (A) - **Explanation**: Acetic acid (CH₃COOH) reacts with ammonia (NH₃) to form an ammonium salt. The reaction can be represented as: \[ CH₃COOH + NH₃ \rightarrow CH₃COONH₄ \] Here, the product (A) is ammonium acetate (CH₃COONH₄). **Hint**: Identify the products of an acid-base reaction. ### Step 2: Heating the Ammonium Salt - **Reaction**: (A) → (B) upon heating - **Explanation**: When ammonium acetate is heated, it undergoes dehydration, losing a water molecule (H₂O) to form an amide: \[ CH₃COONH₄ \xrightarrow{\text{Heat}} CH₃C(O)NH₂ + H₂O \] The product (B) is acetamide (CH₃C(O)NH₂). **Hint**: Consider what happens during the dehydration of an ammonium salt when heated. ### Step 3: Reaction with P₂O₅ - **Reaction**: (B) → (C) using P₂O₅ - **Explanation**: P₂O₅ is a dehydrating agent. When acetamide is treated with P₂O₅, it removes water, leading to the formation of a nitrile: \[ CH₃C(O)NH₂ \xrightarrow{P₂O₅} CH₃C≡N + H₂O \] The product (C) is acetonitrile (CH₃C≡N). **Hint**: Recognize the role of P₂O₅ in removing water and forming a nitrile. ### Step 4: Reduction with Sodium in Ethanol - **Reaction**: (C) + Na + C₂H₅OH → (D) - **Explanation**: Sodium in ethanol acts as a reducing agent. When acetonitrile is reduced, it converts to an amine: \[ CH₃C≡N + 2H \xrightarrow{Na, C₂H₅OH} CH₃CH₂NH₂ \] The product (D) is ethylamine (CH₃CH₂NH₂). **Hint**: Understand the reduction process and the final product formed from a nitrile. ### Final Answer The product (D) in the sequence of reactions is **ethylamine (CH₃CH₂NH₂)**.

To determine the product (D) in the given sequence of reactions, we will analyze each step carefully. ### Step 1: Reaction of Acetic Acid with Ammonia - **Reaction**: CH₃COOH + NH₃ → (A) - **Explanation**: Acetic acid (CH₃COOH) reacts with ammonia (NH₃) to form an ammonium salt. The reaction can be represented as: \[ CH₃COOH + NH₃ \rightarrow CH₃COONH₄ \] ...
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MARVEL PUBLICATION-ORGANIC COMPOUNDS CONTAINGING NITROGEN -TEST YOUR GRASP
  1. The product (D ) in the following sequence of reaction is CH(...

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  2. IUPAC name of ethyl amine is

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  3. Acetaldoxime on reduction by Na and alcohol produces

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  4. (CH(3))(3) N is

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  5. Ethyl amine reacts with which of the following to give ethyl am...

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  6. Trimethyl amine is less basic than methyl amine because

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  7. n-butyl amine and isobuty amine are

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  8. The true statement about ethylamine is

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  9. The reaction which is given only by primary amines is

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  10. A amine produces yellow oily compound on reaction with nitrous ...

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  11. Which of the following produces diacetyl derivative on reaction w...

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  12. According to Lewis concept R- NH(2)

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  13. Which of the following is quarternary ammonium salt ?

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  14. Methylation of methyl amine gives 1^(st) product as

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  15. Which of the following is absorbed by dilute HCI ?

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  16. Which of the following produces HNO(2) acid ?

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  17. The amine which reacts with NaNO2 and dil. HCl to give yellow oily com...

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  18. Ethyl bromide reacts with excess of alcoholic ammonia the majo...

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  19. When ethylamine is heated with excess of acetic anhydride it giv...

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  20. Dimethanamine is the IUPAC name of

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  21. Methyl amine is obtained by reduction of nitromethane by using w...

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