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99% at a first order reaction was comple...

`99%` at a first order reaction was completed in `32 min`. When will `99.9%` of the reaction complete.

A

56 min

B

26 min

C

19 min

D

48 min

Text Solution

Verified by Experts

`x_1=99/100=0.99a`
`k = 2.303/32 log. (a)/(a-0.99a)`
`= 2.303/32 log 10^2 =2.303/ 16 mi n^(-1)`
`x_2 = 99.9/100=0.999a`
`t_(99.9%)=2.303/100log. (a)/(a-0.999a)`
`= 2.303/k log 10^3 = (3xx 2.303)/2.303xx 16`
=48 min.
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