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Limiting molar conductivity of NH(4)OH(i...

Limiting molar conductivity of `NH_(4)OH(i.e.^^_(m)^(@)(NH_(4)OH)` is equal to:

A

`^^_(m(NH_(4)Cl))^(@)+^^_(m(NaCl))^(@)-^^_(m(NaOH))^(@)`

B

`^^_(m(NaOH))^(@)+^^_(m(NaCl))^(@)-^^_(m(NII_(4)Cl))`

C

`^^_(m(NH_(4)OH)+)^(@) ^^_(m(NH_(4)Cl))^(@)-^^_(m(HCl))^(@)`

D

`^^_(m(NH_(4)Cl)+)^(@)^^_(m(NaOH))^(@)-^^_(m(NaCl))^(@)`

Text Solution

Verified by Experts

The correct Answer is:
D

`^^_(m(NH_(4)Cl))^(@)=^^_(mNH_(4)^(+))^(@)+^^_(mCl^(-))^(@)`
`^^_(m(NaOH))^(@)=^^_(mNa^(+))^(@)+^^_(m_(OH^(-)))^(@)`
`^^_(m(NaCl))^(@)=^^_(m_(Na^(+)))^(@)+^^_(m_(Cl^(-)))^(@)`
`therefore ^^_(m(NH_(4)^(+)))^(@)+^^_(m(OH^(-)))^(@)`
`=^^_(m(NH_(4)^(+)))^(@)+^^_(m(Cl^(-)))^(@) + ^^_(m(Na^(+)))^(@)`
`+^^_(m(OH^(-)))^(@)[^^_(m(Cl))^(@)+^^_(m(Cl^(-)))]`
`^^_(m(NH_(4)OH))^(@) =^^_(m(NH_(4)Cl))^(@)+^^_(m(NaOH))-^^_(m(NaCl))^(@)`
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