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Consider the following complex ions, P, ...

Consider the following complex ions, P, Q and R.
`P=[FeF_(6)[^(3-),Q=[V(H_(2)O)_(6)]^(2+) and R=[Fe(H_(2)O)_(6)]^(2+)` The correct order of the complex ions, according to their spin-only magnetic moment values (in B.M.) is

A

`R lt Q lt P`

B

`Q lt R lt P`

C

`R lt P lt Q`

D

`Q lt P lt R`

Text Solution

Verified by Experts

The correct Answer is:
B

The electronic configuration of central ion in complex ions P, Q and R are

Higher the no. of unpaired electron(s), higher will be magnetic moment. Thus the correct order of spin only magnetic moment is QltRltP.
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