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Which of the following are inner orbital...

Which of the following are inner orbital complex (i.e., involving `d^(2)sp^(3)` hybridisation) and is paramangetic in nature?

A

`[Mn(CN)_(6)]^(3-),[Fe(CN)_(6)]^(3-),[Co(C_(2)O_(4))_(3)]^(3-)`

B

`[MnCl_(6)]^(3-),[FeF_(6)]^(3-),[CoF_(6)]^(3-)`

C

`[Mn(CN)_(6)]^(3-),[Fe(CN)_(6)]^(3-)`

D

`[MnCl_(6)]^(3-),[Fe(CN)_(6)]^(3-),[Co(C_(2)O_(4))_(3)]^(3-)`

Text Solution

Verified by Experts

The correct Answer is:
C

`[Mn(CN)_(6)]^(3-) and [Fe(CN)_(6)]^(3-)` are inner orbital complexes and paramagnetic while `[Co(C_(2)O_(4))_(3)]^(3-)` is diamagnetic in nature.
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