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Give name ofthe complex, name should spe...

Give name ofthe complex, name should specify the position of ligands.

A

bistransphosphinecarbonylchloroiridium (II)

B

carbonylchlorobistransphosphineiridium (Ill)

C

carbonylchlorobistransphosphineiridium (I)

D

chlorocarbonylbistransphosphineiridium (I)

Text Solution

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The correct Answer is:
C

naming should be done alphabetically. Hence, 'carbonyl' is followed bty 'chloro' and then 'phosphine' bis used to denote two same groups and trans denotes the position. 'CO', and `'PH_(3)'` are neutral ligands. Only `Cl^(-)` is charged.hence oxidation state of Ir is `(+I)` only. thus correct IUPAC name of given complex is carbonylchlorobistransphosphineiridium (l).
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