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The solubility of PbI(2) is 0.0013M. The...

The solubility of `PbI_(2)` is `0.0013`M. Then the solubility product of `PbI_(2)` is

A

`2.2xx10^(-9)`

B

`8.8xx10^(-9)`

C

`6.8xx10^(-6)`

D

`0.8xx10^(-6)`

Text Solution

Verified by Experts

The correct Answer is:
B

Equilibrium equation is
`PbI_(2)(s)rarrPb^(2+)(aq.)+2I^(-)(aq.)`
The solubility of `PbI_(2)` is `0.0013mol L^(-1)` or `1.3xx10^(-3)mol L^(-1)`
`:. C_(Pb^(2+))=1.3xx10^(-3)M`
`C_(I^(-))=2xx1.3xx10^(-3)mol L^(-1)`
`=2.6xx10^(-3)mol L^(-1)`
`K_(sp)=C_(Pb^(2+)C_(I^(-))`
`=(1.3xx10^(-3))(2.6xx10^(-3))^(2)`
`=8.8xx10^(-9)`
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