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When phenol is heated with CHCl(3) and a...

When phenol is heated with `CHCl_(3)` and alcoholic `KOH`, salicylaldehyde is produce. This reaction is known as

A

Rosenumud's reaction

B

Reimer - Tiemann reaction

C

Friedel - Craft's reaction

D

Sommelet reaction

Text Solution

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The correct Answer is:
To determine the name of the reaction when phenol is heated with chloroform (CHCl3) and alcoholic KOH, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants in this reaction are phenol (C6H5OH), chloroform (CHCl3), and alcoholic potassium hydroxide (KOH). 2. **Understand the Reaction Conditions**: The reaction takes place under heating conditions, which is essential for the reaction to proceed. 3. **Recognize the Product**: The product formed from this reaction is salicylaldehyde (C7H6O), which is a compound with a hydroxyl group (-OH) and an aldehyde group (-CHO) on adjacent carbon atoms. 4. **Recall the Type of Reaction**: The reaction between phenol and chloroform in the presence of a strong base (like alcoholic KOH) is a specific type of reaction in organic chemistry. 5. **Name the Reaction**: This reaction is known as the **Reimer-Tiemann reaction**. It is a well-known reaction that involves the ortho-formylation of phenols. 6. **Conclusion**: Therefore, when phenol is heated with CHCl3 and alcoholic KOH, salicylaldehyde is produced, and this reaction is called the Reimer-Tiemann reaction. ### Final Answer: The reaction is known as the **Reimer-Tiemann reaction**. ---

To determine the name of the reaction when phenol is heated with chloroform (CHCl3) and alcoholic KOH, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants in this reaction are phenol (C6H5OH), chloroform (CHCl3), and alcoholic potassium hydroxide (KOH). 2. **Understand the Reaction Conditions**: The reaction takes place under heating conditions, which is essential for the reaction to proceed. ...
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Knowledge Check

  • Phenol is heated with CHCl_(3) and alcoholic KOH when salicylaldehyde is produced. This reaction is known as:

    A
    Rosenmund.s reaction
    B
    Reimer - Tiemann reaction
    C
    Friedel - crafts reactions
    D
    Sommelet reaction
  • Phenol is heated with CHCl_(3) and alcoholic KOH when salicylaldehyde is produced. This reaction is known as:

    A
    Rosenmund.s reaction
    B
    Reimer - Tiemann reaction
    C
    Friedel - crafts reactions
    D
    Sommelet reaction
  • Phenol is heated with CHCl_(3) and alcoholic KOH when salicydehyde is produced. The reaction is known as

    A
    Rosenmund's reaction
    B
    Reimer-Tiemann reaction
    C
    Friedal-Craft's reaction
    D
    Smmelet reaction
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