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CuSO(4).5H(2)O, a hydrated salt, is a co...

`CuSO_(4).5H_(2)O`, a hydrated salt, is a coordination compound of `Cu^(2+)` ions with `H_(2)O` molecules as the ligands. It can also be regarded as a solution of

A

a solid in a liquid

B

a liquid in a solid

C

a solid in a solid

D

a liquid in a liquid

Text Solution

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The correct Answer is:
2

Because its composition changes on heating unlike a compound.

These changes are reversible, the colourless anhydrous salt turning blue on contact with water to form crystal of blue vitriol: `[Cu(H_(2)O)_(4)]^(2+) SO_(4)^(2-). H_(2)O`, four water molecular are coordinated to the central to the central metal ion `(Cu^(2+))` while the fifth water molecule is hydrogen bonded to sulphate ion.
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Assertion : CuSO_(4).5H_(2)O on heating to 250^(@)C losses all the five H_(2) O molecules and becomes anhydrous. Reason : All five H_(2) O molecules are coordinated to the central Cu^(2+) ion.