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The degree of dissociation (alpha) of a ...

The degree of dissociation `(alpha)` of a weak electrolyte, `A_(x)B_(y)` is related to van't Hoff's factor `(i)` by the expression:

A

`alpha=(i-1)/((x+y-1))`

B

`alpha=(i-1)/(x+y+1)`

C

`alpha=(x+y-1)/(i-1)`

D

`alpha=(x+y+1)/(i-1)`

Text Solution

Verified by Experts

The correct Answer is:
1

`{:(,A_(x)B_(y),hArr,xA^(y+),+,yB^(x-)),("Total moles before ionization",1mol,,0mol,,0mol),("Total moles after ionization",(1-alpha)mol,,(xalpha)mol,,(yalpha)mol):}`
`i=("Total moles after ionization")/("Total moles before ionization")`
`=((1-alpha)+(xalpha)+(yalpha))/1`
`i=1+(x+y-1)alpha`
or `alpha=(i-1)/((x+y-1))`
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