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The boiling point of 0.2 mol kg^(-1) sol...

The boiling point of `0.2 mol kg^(-1)` solution of `X` in water is greater than equimolal solution of `Y` in water. Which of the following statements is true in this case?

A

Y is undergoing dissociation in water while X indergoes no change

B

X is undergoing dissociation in water

C

Molecular mass of X is greater than the molecular mass of Y

D

Molecular of X is less than the molecular mass of Y.

Text Solution

Verified by Experts

The correct Answer is:
2

We have
`DeltaT_(b)=iK_(b)m`
For equimolal aqueous solutions, `K_(b)` and m are identical. Thus, `DeltaT_(b)` is directly proportional to the value of van't hoff factor. The higher boiling point of aqueous solution of `X` clearly indicates that. It has higher value of i. In case of dissociation, `igt 1`.
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