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The least stable hydride is...

The least stable hydride is

A

`PH_(3)`

B

`AsH_(3)`

C

`SbH_(3)`

D

`BiH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
4

The hydrides show regular graduation in their properties ,The thermal stability of the hybrides decreases (due to decrease fo `Delta_("diss")H^(Ɵ)(E-H)]` as we move from `NH_(3)` to `BiH_(3)`. Thus `NH_(3)` is most stable ,the stability of `PH_(3), AsH_(3)` and `SbH_(3)` decreases progrssively while `BiH_(3)` is the least stable.
Order of thermal stability:
`NH_(3) gt PH_(3) gt AsH_(3) gt SbH_(3) gt BiH_(3)`
`BiH_(3)` is so unstable that it has a half -life of only `20` minutes at ordinary temperatures.
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Knowledge Check

  • Least stable hydide is :

    A
    stannane
    B
    silane
    C
    plumbane
    D
    germane
  • The least stable hydride of 15th group elements is

    A
    `NH_(3)`
    B
    `PH_(3)`
    C
    `AsH_(3)`
    D
    `BiH_(3)`
  • The least stable hydride of 15^(th) group elements is __________.

    A
    `NH_(3)`
    B
    `PH_(3)`
    C
    `SbH_(3)`
    D
    `BiH_(3)`
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