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The appropriate reduction potentials sug...

The appropriate reduction potentials suggest that hydroxylamine should disproportionate .It disproportionate slowly in acidic solutions to give

A

`N_(2)O`and `NH_(4)^(+)`

B

`N_(2)` and `NH_(3)`

C

`NO` and `NH_(3)`

D

`NO_(2)` and `NH_(4)^(+)`

Text Solution

Verified by Experts

The correct Answer is:
1

`4[overset(-1)(N)H_(2)OH.H]^(+)rarroverset(+1)N_(2)O+2overset(-3)NH_(4)^(+)+2H^(+)+3H_(2)O`
It disproportionatesrapidly in alkaline solutions:
`3overset(-1)(N)H_(2)OHrarroverset(0)N_(2)+overset(-3)NH_(3)+3H_(2)O`
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