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which of the following compounds is form...

which of the following compounds is formed when `ZnSO_(4)`is treated with liquor ammonia?

A

`Zn(OH)_(2).Zn(NH_(3))_(4)SO_(4)`

B

`Zn(OH)_(2).ZnSO_(4).NH_(3)`

C

`[Zn(NH_(3))_(4)]SO_(4)`

D

`[Zn(NH_(3))_(6)]SO_(4)`

Text Solution

Verified by Experts

The correct Answer is:
3

Zinc hydroxide is formed which dissolved in the form of complex in excess of `NH_(4)OH.`
`ZnSO_(4)+2NH_(4)OHrarrZn(OH)_(2)+(NH_(4))_(2)SO_(4)`
`Zn(OH)_(2)+(NH_(4))_(2)SO_(4)+2NH_(4)OHrarr[Zn(NH_(3))_(4)]SO_(4)+4H_(2)O`
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